Also is there something I need to do to the RODI unit now that its city and they use clorine?
This time the water was just filtered with the carbon block and sedement filters because it was a rush due to my power was out for 8 hours and I wanted to do a quick water change. Its is well water.
Well that would explain high PO4. You should never use water that hasn't been run through everything including the membrane and the resin. And a salinity of 1.030 would explain high everything. Make sure you are using the ro/di properly, get a refractometer with calibration solution, and try another batch of RC, I am bet everything will be fine.
For your PO4 I'd suggest putting a Hanna checker on your wish list.